Versatile Methods for Preparation of New Cyclometalated Gold(III) Complexes
收藏Figshare2016-02-20 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Versatile_Methods_for_Preparation_of_New_Cyclometalated_Gold_III_Complexes/2484151
下载链接
链接失效反馈官方服务：
资源简介：
Versatile methods for the high-yield syntheses of new cyclometalated gold(III) complexes are described. Mono- or dialkylated or arylated gold(III) complexes are selectively obtained from reaction of Au(OCOCF3)2(tpy) (tpy = 2-(p-tolyl)pyridine) with either RMgX or RLi, respectively. Specifically, AuMe2(tpy) and AuPh2(tpy) were prepared with the respective lithium reagents, and AuBrMe(tpy), AuBrEt(tpy), and AuBrPh(tpy) were prepared with Grignard reagents. The molecular structures of compounds Au(OCOCF3)2(tpy) and AuMe2(tpy) were determined by single crystal X-ray diffraction.
创建时间：
2016-02-20
