Highly Enantioselective and Diastereoselective 1,3-Dipolar Cycloaddition Reactions between Azomethine Imines and 3-Acryloyl-2-oxazolidinone Catalyzed by Binaphthyldiimine−Ni(II) Complexes
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https://figshare.com/articles/dataset/Highly_Enantioselective_and_Diastereoselective_1_3_Dipolar_Cycloaddition_Reactions_between_Azomethine_Imines_and_3_Acryloyl_2_oxazolidinone_Catalyzed_by_Binaphthyldiimine_Ni_II_Complexes/3034723
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资源简介：
We have found the first example of high levels of asymmetric induction (97−74% ee) along with high diastereoselectivity (>99:1−64:36) in
dipole-HOMO-/dipolarophile-LUMO-controlled asymmetric 1,3-dipolar cycloaddition reactions between fused azomethine imines and 3-acryloyl-2-oxazolidinone using a chiral BINIM−Ni(II) complex as a chiral Lewis acid catalyst.
创建时间：
2016-02-29
