An Efficient and Convenient Reaction Protocol to Organoimido Derivatives of Polyoxometalates

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An Efficient and Convenient Reaction Protocol to Organoimido Derivatives of Polyoxometalates

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2016-08-18

Organic−Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes

多金属氧酸盐

分子磁体研究

Two novel organic−inorganic hybrid compounds based on Anderson-type polyoxoanions, [Cu2(bpy)2(μ-ox)][Al(OH)7Mo6O17] (1) and [Cu2(bpy)2(μ-ox)][Cr(OH)7Mo6O17] (2), have been synthesized and characterize

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A Highly Selective Manganese-Catalyzed Synthesis of Imines under Phosphine-Free Conditions

亚胺合成

催化脱氢偶联

An efficient and highly selective phosphine-free NN-manganese(I) complex catalyst system was developed for the acceptorless dehydrogenative coupling of alcohols with amines to form imines. The coupli

NIAID Data Ecosystem50

Cobalt(II)/Nickel(II)-Centered Keggin-Type Heteropolymolybdates: Syntheses, Crystal Structures, Magnetic and Electrochemical Properties

多金属氧酸盐

磁电性质

New Keggin-type cobalt(II)/nickel(II)-centered heteropolymolybdates, (C3H5N2)6[CoIIMo12O40]·10H2O (1) and (NH4)3(C4H5N2O2)3[NiIIMo12O40] (2), were isolated and characterized by IR, UV–vis, single-crys

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Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions. 3. Structure and Characterization of [Cu(enMe) 2 ] 2 {[Cu(enMe) 2 (H 2 O)] 2 [Cu 6 (enMe) 2 ( B - a -SiW 9 O 34 ) 2 ]}·4H 2 O

多金属氧酸盐

晶格结构

A novel sandwich-type polyoxometalate incorporating a unique hybrid hexanuclear copper cluster, [Cu(enMe)2]2{[Cu(enMe)2(H2O)]2[Cu6(enMe)2(B-a-SiW9O34)2]}·4H2O (1, enMe = 1,2-diaminopropane), has been

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Copper(II) Complexes of Tetradentate Pyridyl Ligands Supported on Keggin Polyoxometalates: Single-Crystal to Single-Crystal Transformations Promoted by Reversible Dehydration Processes

配位化学

多金属氧酸盐

Two new hybrid compounds constructed from Keggin type polyoxometalates and copper(II) complexes of tetradentate ligands containing amine and pyridyl groups, namely [Cu(bpmen)(H2O)][SiW12O40{Cu(bp

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An Efficient and Convenient Reaction Protocol to Organoimido Derivatives of Polyoxometalates

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