Enantioselective Ring-Opening/Oxidative Phosphorylation and P‑Transfer Reaction of Cyclic Diaryliodoniums
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https://figshare.com/articles/dataset/Enantioselective_Ring-Opening_Oxidative_Phosphorylation_and_P_Transfer_Reaction_of_Cyclic_Diaryliodoniums/9929831
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资源简介：
A Cu-catalyzed
enantioselective ring-opening/oxidative phosphorylation
reaction of cyclic diaryliodonium salts and diarylphosphine oxides
in the presence of TEMPO was reported. 18O-Labeled experiments
showed that the reaction proceeded via oxidation, followed by C–O
bond formation. Furthermore, atropisomeric phosphine oxides were prepared
via a t-BuLi-mediated P-transfer reaction. Computational
studies elucidated that the phosphine oxide transfer was through a
concerted C–P bond formation and P–O bond-dissociation
process.
创建时间：
2019-09-26
