Development of a Porous Coordination Polymer with a High Gas Capacity Using a Thiophene-Based Bent Tetracarboxylate Ligand

A new porous coordination
polymer (PCP) based on a ligand with a unique bent angle bearing a
thiophene-bridged bent carboxylate ligand and the Cu2+ ion
was synthesized and structurally characterized. The structure has
a pillared-layer framework based on a kagomé-like layer with
aromatic partition groups. It exhibits a high CO2 uptake
of 180 mL­(STP)/g at 1 bar, and 400 mL­(STP)/g at 30 bar at 273 K. The
uptakes of C2H2 and C2H4 reach 164 and 160 mL­(STP)/g at 298 K and 1 bar, with good selectivity
of C2H2 and C2H4 over
CH4, both of which are among the highest levels of reported
PCPs.