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Synthesis and Structure of an Intramolecularly Coordinated Diaryltelluronic Acid and Its Dimethyl Ester

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_an_Intramolecularly_Coordinated_Diaryltelluronic_Acid_and_Its_Dimethyl_Ester/2564650
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The oxidation of the telluroxane cluster (8-Me2NC10H6Te)6O8(OH)2 (4) or the diaryl ditelluride (8-Me2NC10H6Te)2 (7) using H2O2 provided the diarylditelluronic acid [8-Me2NC10H6Te­(O)­(OH)2]2(O) (6), which is the second member of this compound class and the first one to contain an intramolecularly coordinated substituent. Attempts at recrystallizing 6 from Methanol provided the partial ester [8-Me2NC10H6Te­(O)­(OH)­(OMe)]2(O) (8). In addition structural motifs of known diaryltelluronic acids were compared using DFT calculations.
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2016-02-22
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