Enantioselective Desymmetrization via Carbonyl-Directed Catalytic Asymmetric Hydroboration and Suzuki–Miyaura Cross-Coupling
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https://figshare.com/articles/dataset/Enantioselective_Desymmetrization_via_Carbonyl_Directed_Catalytic_Asymmetric_Hydroboration_and_Suzuki_Miyaura_Cross_Coupling/2194228
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资源简介：
The rhodium-catalyzed enantioselective
desymmetrization of symmetric
γ,δ-unsaturated amides via carbonyl-directed catalytic
asymmetric hydroboration (directed CAHB) affords chiral secondary
organoboronates with up to 98% ee. The chiral γ-borylated products
undergo palladium-catalyzed Suzuki–Miyaura cross-coupling via
the trifluoroborate salt with stereoretention.
创建时间：
2016-02-14
