Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes
收藏NIAID Data Ecosystem2026-03-14 收录
下载链接：
https://figshare.com/articles/dataset/Reductive_Elimination_from_Sterically_Encumbered_Ni_Polypyridine_Complexes/21183486
下载链接
链接失效反馈官方服务：
资源简介：
Herein we disclose the synthesis of sterically encumbered
dialkylnickel(II)
complexes bearing 2,9-dimethyl-1,10-phenanthroline ligands. A comparison
with their unsubstituted analogues by both X-ray crystallography and
theoretical calculations revealed significant distortions in their
molecular structures. Eyring plots along with stoichiometric and photoexcitation
studies revealed that sterically encumbered dialkylnickel(II) complexes
enable facile C(sp3)–C(sp3) reductive elimination, thus offering an
improved understanding of Ni catalysis.
创建时间：
2022-09-21
