Yttrium Alkyl and Hydrido Complexes Containing a Tridentate-Linked Amido-Cyclopentadienyl Ligand
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https://figshare.com/articles/dataset/Yttrium_Alkyl_and_Hydrido_Complexes_Containing_a_Tridentate_Linked_Amido_Cyclopentadienyl_Ligand/3361966
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资源简介：
A tridentate-linked amido-cyclopentadienyl ligand (C5Me4CH2SiMe2NCH2CH2NMe2)2- (L)
was coordinated at yttrium to give the alkyl complex [Y(L)(CH2SiMe3)(THF)] (2), which reacts
with H2 to give the THF-free dimeric hydride [Y(L)(μ-H)]2 (3). Styrene inserted into the
yttrium−hydride bond of 3 at 60 °C to give the 1-phenylethyl complex [Y(L){CH(CH3)Ph}]
(4).
创建时间：
2016-05-07
