Samarium(III)-Catalyzed C(sp3)–H Bond Activation: Synthesis of Indolizines via C–C and C–N Coupling between 2‑Alkylazaarenes and Propargylic Alcohols
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A new rare earth metal and samarium-catalyzed C(sp3)–H bond activation is reported in which 2-alkylazaarenes and propargylic alcohols were converted to indolizines. This process operates under mild conditions and solvent-free conditions. A broad scope of coupling partners has been established, and a likely mechanism has also been suggested.
创建时间:
2016-02-18



