Porous Nonlinear-Optical Material Based on a Twin-Nest-Shaped Heterothiometallic Cluster: {[NH<sub>4</sub>][W<sub>2</sub>O<sub>2</sub>S<sub>6</sub>Cu<sub>6</sub>I<sub>3</sub>(4,4‘-bipy)<sub>4</sub>]·5H<sub>2</sub>O}<i><sub>n</sub></i>
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A novel 3D porous coordination complex based on a twin-nest-shaped heterothiometallic cluster has been synthesized and characterized. The complex shows an unprecedented structure type and interesting nonlinear-optical properties. Its gas sorption property was studied and shown to be comparable to that of previously reported metal−organic frameworks.
创建时间：
2016-06-03
