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NMR spectra of substituted alpha-aminonitrilecyclohexane mixtures.

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The NMR spectra of product mixtures resulting from the reaction of substituted cyclohexanones with an amine hydrochloride and potassium cyanide in water. The resulting products exhibit a preference for one of the two possible geometric isomers due to diastereofacial selectivity during the attack by the cyanide ion on the intermediate iminium. A pdf file is included as a key to the identity of the folders containing the NMR data on the individual compounds.
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2023-08-13
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