Parallel and Inclined (1D → 2D) Interlacing Modes in New Polyrotaxane Frameworks [M<sub>2</sub>(bix)<sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>] [M = Zn(II), Cd(II); Bix = 1,4-Bis(imidazol-1-ylmethyl)benzene]
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The reactions of MII sulfates (M = Zn, Cd) with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) yield the novel interesting coordination networks [M2(bix)3(SO4)2], containing 1D polymeric motifs of alternating rings and rods, which show extended rotaxane-like mechanical links producing 2D sheets via unprecedented parallel (M = Zn) or inclined (M = Cd) interlacing modes of the chains.
创建时间：
2016-05-12
