Highly Selective Catalyst-Dependent Competitive 1,2-C→C, -O→C, and -N→C Migrations from β‑Methylene-β-silyloxy-β-amido-α-diazoacetates
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下载链接:
https://figshare.com/articles/dataset/Highly_Selective_Catalyst_Dependent_Competitive_1_2_C_C_O_C_and_N_C_Migrations_from_Methylene_silyloxy_amido_diazoacetates/2448841
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资源简介:
Transition-metal catalysts direct 1,2-C→C, -O→C,
and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates
with high selectivity. The key to achieving this unique display of
differential selectivities relies on steric and stereoelectronic control
by their catalytically generated metal carbenes.
创建时间:
2013-01-30



