Fluoreno[4,3-c]fluorene: A Closed-Shell, Fully Conjugated Hydrocarbon
收藏Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Fluoreno_4_3_i_c_i_fluorene_A_Closed_Shell_Fully_Conjugated_Hydrocarbon/2525629
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资源简介：
The synthesis and optoelectronic properties of 24 π-electron, formally antiaromatic 4,11-di-t-butyl-1,8-dimesitylfluoreno[4,3-c]fluorene (FF) are presented. The solid-state structure shows that the outer rings are aromatic, while the central four rings possess a bond-localized 2,6-naphthoquinone dimethide motif (in red). The biradical character of FF is assessed experimentally and computationally; the results of which implicate a closed-shell ground state.
创建时间：
2016-02-21
