Oxidative Addition across Sb–H and Sb–Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate
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https://figshare.com/articles/dataset/Oxidative_Addition_across_Sb_H_and_Sb_Sb_Bonds_by_an_Osmium_Carbonyl_Cluster_Trapping_the_Intermediate/2324701
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资源简介：
The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H
bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product.
In both cases, the intermediate from the oxidative addition reaction
was trapped as a W(CO)5 adduct.
创建时间：
2014-02-10
