Three-Dimensional Frameworks of Cubic (NH<sub>4</sub>)<sub>5</sub>Ga<sub>4</sub>SbS<sub>10</sub>, (NH<sub>4</sub>)<sub>4</sub>Ga<sub>4</sub>SbS<sub>9</sub>(OH)·H<sub>2</sub>O, and (NH<sub>4</sub>)<sub>3</sub>Ga<sub>4</sub>SbS<sub>9</sub>(OH<sub>2</sub>)·2H<sub>2</sub>O
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Three new isostructural open-framework sulfides, (NH4)5Ga4SbS10 (1), (NH4)4Ga4SbS9(OH)·H2O (2a), and (NH4)3Ga4SbS9(H2O)·2H2O (2b), were synthesized under basic hydrothermal conditions using ammonium hydroxide as the structure-directing agent. The structures feature a three-dimensional open framework comprised of adamantane [Ga4Q10]8− clusters linked with Sb3+ centers. The compounds are wide gap semiconductors, crystallize in the chiral space group P213, and represent a new structure type. They exhibit nonlinear optical properties.
创建时间：
2009-12-07
