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A Structurally Rigid Bis(amido) Ligand Framework in Low-Coordinate Ni(I), Ni(II), and Ni(III) Analogues Provides Access to a Ni(III) Methyl Complex via Oxidative Addition

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/A_Structurally_Rigid_Bis_amido_Ligand_Framework_in_Low_Coordinate_Ni_I_Ni_II_and_Ni_III_Analogues_Provides_Access_to_a_Ni_III_Methyl_Complex_via_Oxidative_Addition/2365996
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资源简介:
A structurally persistent bis-amido ligand framework capable of supporting nickel compounds in three different oxidation states has been identified. A highly unusual, isolable Ni­(III) alkyl species has been prepared and characterized via a rare example of a two-electron oxidative addition of MeI to Ni­(I).
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2016-02-18
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