Octaiodoporphyrin
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Octaiodoporphyrin/2102428
下载链接
链接失效反馈官方服务：
资源简介：
Interaction of 3,4-diiodopyrrole
with 4-trifluoromethylbenzaldeyde under carefully optimized, Lindsey-type
conditions at −10 °C has led to the synthesis of the first
β-octaiodoporphyrin, H2[I8TpCF3PP]. The free ligand readily yielded Ni, Cu, and Zn
complexes, which all proved amenable to single-crystal X-ray structure
analyses. The zinc complex Zn[I8TpCF3PP] exhibits the most saddled porphyrin core for any simple
porphyrin known to date and a dramatically red-shifted optical spectrum
with a Soret maximum at 495 nm.
创建时间：
2016-02-12
