Octaiodoporphyrin
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
Interaction of 3,4-diiodopyrrole with 4-trifluoromethylbenzaldeyde under carefully optimized, Lindsey-type conditions at −10 °C has led to the synthesis of the first β-octaiodoporphyrin, H2[I8TpCF3PP]. The free ligand readily yielded Ni, Cu, and Zn complexes, which all proved amenable to single-crystal X-ray structure analyses. The zinc complex Zn[I8TpCF3PP] exhibits the most saddled porphyrin core for any simple porphyrin known to date and a dramatically red-shifted optical spectrum with a Soret maximum at 495 nm.
创建时间：
2016-02-12
