Core-Hole Spectroscopy of Energy Conversion and Storage-Related Phosphorus Compounds Using Soft and Hard X rays (Experimental XANES dataset)
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Dear readers, In the following, we provide the complete experimental X-ray absorption near-edge structure (XANES) spectroscopy dataset given in our investigation of: "Core-Hole Spectroscopy of Energy Conversion and Storage Related-Phosphorus Compounds Using Soft and Hard X-rays". This dataset includes partial fluorescence yield (PFY)-XANES at P <em>K</em>-edge and P <em>L</em><sub>2,3</sub>-edge of 9 solid P-containing compounds with different chemical environments and oxidation states ranging from P(-III) to P(V), namely: GaP, InP, red phosphorus (Red-P), H<sub>3</sub>PO<sub>3</sub>, Na<sub>2</sub>H<sub>2</sub>P<sub>2</sub>O<sub>6</sub>, H<sub>3</sub>PO<sub>4</sub>, KH<sub>2</sub>PO<sub>4</sub>, Na<sub>2</sub>HPO<sub>4</sub>, InPO<sub>4</sub>. Additionally, P <em>K</em>-edge XANES spectra of aqueous P-containing acids: 1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>4</sub>, 1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>3</sub>, as well as the solution mixture of 1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>3</sub> + 1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>4</sub>, and 0.1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>3</sub> + 1 mol dm<sup>-3</sup> H<sub>3</sub>PO<sub>4</sub>.
