An Organic Intermolecular Dehydrogenative Annulation Reaction
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https://figshare.com/articles/dataset/An_Organic_Intermolecular_Dehydrogenative_Annulation_Reaction/4873199
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资源简介：
The
discovery of a direct method for the synthesis of three-ring
heterocyclic carbazoles from unactivated arenes and anilides by a
metal-free (organic) intermolecular dehydrogenative annulation reaction
under ambient laboratory conditions is reported. Iodine(III) was used
as the sole reagent either stoichiometrically from inexpensive phenyliodine
diacetate or organocatalytically by in situ generation from PhI–mCPBA. In a single step, three C(sp2)–H
bonds and one N(sp3)–H bond are functionalized from
two different arenes for tandem C–C and C–N bond formation
reactions.
创建时间：
2017-04-13
