A Novel Metal-Binding Mode of Thymine Nucleobases: N(3) and O(4) Chelation<sup>†</sup>
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The syntheses and crystal structures of the first examples of an anionic 1-methylthymine [deprotonated at the endocyclic NH group N(3)] acting as a chelating ligand for the cis-Pd(C6F3H2)2 and cis-Pd(C6F5)2 moieties through N(3) and O(4) are reported.
创建时间:
2016-06-03



