Synthesis and Characterization of a Stable High-Valent Cobalt Carbene Complex
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_Stable_High_Valent_Cobalt_Carbene_Complex/3187199
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资源简介：
The formally CoIV carbene
Co(OR)2(CPh2) is formed upon the reaction
of diphenyldiazomethane
with the cobalt bis(alkoxide) precursor Co(OR)2(THF)2. Structural, spectroscopic, and theoretical studies demonstrate
that Co(OR)2(CPh2) has significant high-valent
CoIVCPh2 character with non-negligible
spin density on the carbene moiety.
创建时间：
2016-04-29
