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Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Concise_Total_Synthesis_and_Stereochemical_Revision_of_all_Trigonoliimines/2629512
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The concise and enantioselective total syntheses of (−)-trigonoliimines A, B, and C are described. Our unified strategy to all three natural products is based on asymmetric oxidation and reorganization of a single bistryptamine, a sequence of transformations with possible biogenetic relevance. We revise the absolute stereochemistry of (−)-trigonoliimines A, B, and C.
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2016-02-23
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