Pd-Catalyzed π‑Chelation Assisted ortho-C–H Activation and Annulation of Allylarenes with Internal Alkynes
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https://figshare.com/articles/dataset/Pd_Catalyzed_Chelation_Assisted_i_ortho_i_C_H_Activation_and_Annulation_of_Allylarenes_with_Internal_Alkynes/2418991
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The synthesis of highly substituted naphthalenes from allylarenes and alkynes is described. This reaction proceeds via π-coordination of an allylic carbon–carbon double bond to the Pd(II) center and is followed by ortho selective C–H bond activation.
创建时间：
2016-02-19
