Vanadium complexes derived from fluoro-substituted Schiff bases: Synthesis, crystal structures, and antimicrobial activity
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Two new vanadium complexes, [VO(L<sup>1</sup>)<sub>2</sub>] (<b>1</b>) and [V<sub>2</sub>O<sub>2</sub>(μ-O)<sub>2</sub>(L<sup>2</sup>)<sub>2</sub>] (<b>2</b>), where L<sup>1</sup> is 2-(cyclohexyliminimethyl)-4,6-difluorophenolate, L<sup>2</sup> is 2,4-difluoro-6-[(2-isopropylaminoethylimino)methyl]phenolate, have been synthesized and characterized by elemental analysis, FT-IR and UV-Vis spectra, and single crystal X-ray determination. The V atom in complex <b>1</b> is in a coordination between trigonal bipyramidal and square pyramidal, and that in complex <b>2</b> is in octahedral coordination. The antibacterial activity of the compounds against various bacteria was assayed. The fluoro-substituted groups play an essential role in the biological process.
提供机构：
Taylor & Francis
创建时间：
2020-02-14
