Visible-Light-Mediated Anti-Regioselective Nitrone 1,3-Dipolar Cycloaddition Reaction and Synthesis of Bisindolylmethanes
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https://figshare.com/articles/dataset/Visible-Light-Mediated_Anti-Regioselective_Nitrone_1_3-Dipolar_Cycloaddition_Reaction_and_Synthesis_of_Bisindolylmethanes/5414614
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资源简介:
The
development of photoredox reactions of 1,3-dipolar cycloaddition
of nitrones with alkenes is reported. It offers an efficient synthetic
method to obtain isoxazolidine derivatives under mild conditions in
synthetically useful yields. The nitrones are cyclized with oxidizable
styrenes and aliphatic alkenes via a polar radical crossover cycloaddition
reaction through photocatalytic reaction without additives. In addition,
bis(indole)methanes can also be prepared through this method.
创建时间:
2017-09-18



