Controlled Synthesis of 1,3,5-Oxadiazin-2-ones and Oxazolones through Regioselective Iodocyclization of Ynamides
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https://figshare.com/articles/dataset/Controlled_Synthesis_of_1_3_5_Oxadiazin_2_ones_and_Oxazolones_through_Regioselective_Iodocyclization_of_Ynamides/2166634
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资源简介:
Two efficient processes based on
the iodocyclization of ynamides
have been developed: (i) N-alkynyl tert-butyloxycarbamates were found to undergo a rare 6-exo-dig ring closure reaction affording 1,3,5-oxadiazin-2-ones by using
acetonitrile as solvent; (ii) In the absence of acetonitrile, N-alkynyl tert-butyloxycarbamates could
undergo 5-endo-dig cyclization providing oxazolones.
创建时间:
2016-02-13



