Exploiting a Difference in Leaving Group Ability: An Approach to β‑Substituted Monofluoroalkenes Using gem-Chlorofluoropropenes
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https://figshare.com/articles/dataset/Exploiting_a_Difference_in_Leaving_Group_Ability_An_Approach_to_Substituted_Monofluoroalkenes_Using_i_gem_i_Chlorofluoropropenes/3153607
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The superior nucleofuge character of chlorine over fluorine was taken advantage of in the selective SN2′ substitution reaction of gem-chlorofluoropropenes, allowing for the clean formation of β-substituted monofluoroalkenes under metal-free conditions. Numerous N-, S-, O-, and C-nucleophiles behaved nicely in this system. Further synthetic transformations of selected monofluoroalkenes were also accomplished.
创建时间：
2016-04-11
