Electronic-structure calculations for the self-association of phenalenyl radical (P•) predict the formation of dimeric species (σ-P2) in which both moieties are connected by a σ-bond with rP-P ∼ 1.59
We present new reaction pathways relevant to low-temperature oxidation in gaseous and condensed phases. The new pathways originate from γ-ketohydroperoxides (KHP), which are well-known products in low
This paper documents in detail the reaction of 1,3-thiazolium-4-olates (thioisomünchnones) with aryl isothiocyanates. Having demonstrated with a chiral model that thionation occurs under these condit