A Concise Route to Pyridines from Hydrazides by Metal Carbene N−H Insertion, 1,2,4-Triazine Formation, and Diels−Alder Reaction
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https://figshare.com/articles/dataset/A_Concise_Route_to_Pyridines_from_Hydrazides_by_Metal_Carbene_N_H_Insertion_1_2_4_Triazine_Formation_and_Diels_Alder_Reaction/2834359
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资源简介：
A simple, new three-step sequence for the conversion of hydrazides into pyridines is reported in which the key steps are N−H insertion by a copper carbene intermediate derived from α-diazo-β-ketoesters into the hydrazide, reaction with ammonium acetate to give 1,2,4-triazines, followed by Diels−Alder reaction with norbornadiene.
创建时间：
2016-02-26
