Expanded Porphyrin-like Structures Based on Twinned Triphenylenes
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https://figshare.com/articles/dataset/Expanded_Porphyrin_like_Structures_Based_on_Twinned_Triphenylenes/2374846
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资源简介:
Triphenylene
twins are intriguing structures, and those bridged
through their 3,6-positions by dipyrromethene units give a new class
of macrocycles that can be viewed as rigid, expanded porphyrin derivatives
in which coplanarity is enforced in a formally antiaromatic π
system. Somewhat surprisingly, however, macrocyclization leads to
significant overall stabilization of the dipyrromethene chromophores.
创建时间:
2016-02-18



