Formal Total Synthesis of (±)-Lycojaponicumin C
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https://figshare.com/articles/dataset/Formal_Total_Synthesis_of_-Lycojaponicumin_C/5026634
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资源简介：
The formal total synthesis of (±)-lycojaponicumin
C has been
accomplished. Key transformations include a Rh-catalyzed formal [3
+ 2] cycloaddition reaction to construct the bicyclic [3.3.0] scaffold
bearing two vicinal quaternary carbon centers, a stereoselective γ-hydroxyl
directed Michael addition to introduce the vinyl group at a bulky
position, and a late-stage ring-closing metathesis reaction to form
the cyclohexanone ring.
创建时间：
2017-05-19
