Deuterodechlorination of Aryl/Heteroaryl Chlorides Catalyzed by a Palladium/Unsymmetrical NHC System
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https://figshare.com/articles/dataset/Deuterodechlorination_of_Aryl_Heteroaryl_Chlorides_Catalyzed_by_a_Palladium_Unsymmetrical_NHC_System/3859773
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资源简介：
The catalytic deuterodechlorination
of aryl/heteroaryl chlorides
was developed with a palladium/unsymmetrical NHC system, and the precisely
controlled introduction of deuterium into a variety of aryl/heteroaryl
compounds was achieved with a high level of efficiency, selectivity,
and deuteration degree. This method was also successfully applied
to the transformation of bioactive agents even in a gram-scale synthesis.
The crystal structure analysis of Pd–NHC complexes led to the
observation of Pd–arene interaction.
创建时间：
2016-10-03
