Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Iron_Catalyzed_Asymmetric_Epoxidation_of_Disubstituted_Enones/2643595
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The combination of Fe(OTf)2 and novel phenanthroline ligands enables the catalytic asymmetric epoxidation of acyclic β,β-disubstituted enones, which have been a heretofore inaccessible substrate class. The reaction provides highly enantioenriched α,β-epoxyketones (up to 92% ee) that can be further converted to functionalized β-ketoaldehydes with an all-carbon quaternary center.
创建时间：
2016-02-23
