Enantioselective Copper-Catalyzed Reductive Michael Cyclizations
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https://figshare.com/articles/dataset/Enantioselective_Copper_Catalyzed_Reductive_Michael_Cyclizations/2820985
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资源简介：
In the presence of siloxanes as stoichiometric reductants, chiral copper-bisphosphine complexes catalyze highly enantioselective reductive Michael cyclizations of substrates containing two α,β-unsaturated carbonyl moieties. The diastereochemical outcome of these reactions is dependent upon whether biaryl- or ferrocene-based chiral bisphosphines are employed.
创建时间：
2016-02-25
