Current therapeutics and prophylactics for malaria are under severe challenge as a result of the rapid emergence of drug-resistant parasites. The human malaria parasite Plasmodium falciparum expresses
Thermodynamic investigations relevant to hydrogen atom transfer by the high-valent iron imido complex [LMesFe⋮NAd]OTf have been undertaken. The complex is found to be weakly oxidizing by cyclic voltam