Selective, Sensitive, and Reversible Detection of Vapor-Phase High Explosives via Two-Dimensional Mapping: A New Strategy for MOF-Based Sensors
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https://figshare.com/articles/dataset/Selective_Sensitive_and_Reversible_Detection_of_Vapor_Phase_High_Explosives_via_Two_Dimensional_Mapping_A_New_Strategy_for_MOF_Based_Sensors/2371579
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资源简介:
A new strategy has been developed
for the effective detection of
high explosives in vapor phase by fluorescent metal–organic
framework (MOF) sensors. Two structurally related and dynamic MOFs,
(Zn)2(ndc)2P·xG [ndc =
2,6-naphthalenedicarboxylate;
P =1,2-bis(4-pyridyl)ethane (bpe) or 1,2-bis(4-pyridyl)ethylene (bpee);
G = guest/solvent molecule], exhibit a two-dimensional signal response
toward analytes of interest in the vapor phase, including aromatic
and aliphatic high explosives (e.g., TNT and RDX). The interaction
between analytes and the MOF has been studied using in situ infrared
absorption spectroscopy and a DFT computational method.
创建时间:
2013-10-02



