Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions
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https://figshare.com/articles/dataset/Hydrolytically_Stable_Nanoporous_Thorium_Mixed_Phosphite_and_Pyrophosphate_Framework_Generated_from_Redox_Active_Ionothermal_Reactions/3124339
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资源简介：
The first thorium
framework compound with mixed-valent phosphorus-based (phosphite and
pyrophosphate) ligands, [BMMim]2[Th3(PO3)4(H2P2O7)3] (ThP-1), was synthesized by ionothermal
reactions concurrent with the partial oxidation of phosphoric acid.
The overall structural topology of ThP-1 highly resembles
that of MOF-5, containing only one type of three-dimensional channels
with a window size of 11.32 Å × 11.32 Å. ThP-1 has a free void volume of 50.8%, making it one of the most porous
purely inorganic actinide-based framework materials. More importantly, ThP-1 is highly stable in aqueous solutions over an extremely
wide pH range from 1 to 14 and thus may find potential applications
in selective ion exchange and catalysis.
创建时间：
2016-04-12
