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Role of Benzylic Deprotonation in Nickel-Catalyzed Benzylic Dehydrogenation

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Zenodo2021-07-09 更新2026-05-25 收录
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Alkylarenes are readily functionalized via the corresponding benzylic anions. Benzylic anions have been used for a range of catalytic reactions, including Ni-catalyzed dehydrogenation. Interestingly, the employment of Zn(TMP)2 for slow and incomplete deprotonation of the benzylic position was observed. This manuscript describes a preliminary investigation into the deprotonation of heteroarenes and its relationship to Ni-catalyzed benzylic dehydrogenation.<br>

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2021-07-09
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