Total Syntheses of Aporphine Alkaloids via Benzyne Chemistry: An Approach to the Formation of Aporphine Cores
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https://figshare.com/articles/dataset/Total_Syntheses_of_Aporphine_Alkaloids_via_Benzyne_Chemistry_An_Approach_to_the_Formation_of_Aporphine_Cores/2120767
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资源简介：
Total
syntheses of lysicamine, (±)-nuciferine, (±)-nornuciferine,
(±)-zanthoxyphylline iodide, (±)-O-methylisothebaine,
and (±)-trimethoxynoraporphine were accomplished by an approach
that involves the formation of aporphine cores through reactions between
an isoquinoline derivative and silylaryl triflates promoted by CsF.
Unprecedented formations of aporphine cores proceeded in good yields
presumably through [4 + 2] cycloaddition reactions followed by hydrogen
migrations.
创建时间：
2016-02-12
