Synthesis and Structure of the First Dinuclear Complex Bridged by a Substituent-Free Gallium Atom
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_the_First_Dinuclear_Complex_Bridged_by_a_Substituent_Free_Gallium_Atom/3361216
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资源简介：
The first dinuclear complex bridged by a
substituent-free gallium atom, Cp*Fe(dppe)(μ-Ga)Fe(CO)4 (1; Cp* = η-C5Me5, dppe = Ph2PCH2CH2PPh2),
was synthesized by the reaction of Cp*Fe(dppe)GaCl2
with K2[Fe(CO)4]. A crystal structure analysis of complex
1 revealed that the geometry around the gallium atom
is essentially linear and the Fe−Ga bonds are significantly shorter than that of usual single bonds. These
structural features indicate that the Fe−Ga bonds bear
significantly unsaturated character.
创建时间：
2016-05-07
