Enantioselective Synthesis of Guaianolides in the Osmitopsin Family by Domino Metathesis
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
Relay metathesis enabled an improved access from (S)-citronellal to the marine trisnorguaiane (−)-clavukerin A. This hydroazulene was applied as an advantageously functionalized building block for the asymmetric synthesis of the sesquiterpene lactone osmitopsin and the proposed structure of 4,5-epoxyosmitopsin using a chemo-, regio-, and diastereoselective diepoxide opening as the key step.
创建时间：
2016-06-27
