Asymmetric Direct Vinylogous Michael Additions of Allyl Alkyl Ketones to Maleimides through Dienamine Catalysis
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https://figshare.com/articles/dataset/Asymmetric_Direct_Vinylogous_Michael_Additions_of_Allyl_Alkyl_Ketones_to_Maleimides_through_Dienamine_Catalysis/2233210
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资源简介：
A direct
catalytic asymmetric γ-regioselective vinylogous
Michael addition of allyl alkyl ketones to maleimides has been developed
through dienamine catalysis of a simple chiral 1,2-diphenylethanediamine,
giving multifunctional products in excellent enantioselectivity and
with high yields. The success of this catalytic strategy relies on
the unique inducing effect of deconjugated β,γ-CC
bond, which facilitates the formation of the otherwise unfavored extended
dienamine species.
创建时间：
2014-11-21
