Stabilization of Unsolvated Europium and Ytterbium Pentafluorophenyls by π-Bonding Encapsulation through a Sterically Crowded Triazenido Ligand
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https://figshare.com/articles/dataset/Stabilization_of_Unsolvated_Europium_and_Ytterbium_Pentafluorophenyls_by_Bonding_Encapsulation_through_a_Sterically_Crowded_Triazenido_Ligand/3254821
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资源简介：
The one-pot transmetalation/deprotonation reaction of the bulky
triazene Dmp(Tph)N3H with bis(pentafluorophenyl)mercury and
europium or ytterbium affords the structurally characterized
unsolvated metal(II) pentafluorophenyl triazenides [Dmp(Tph)N3MC6F5] (M = Eu, Yb; Dmp = 2,6-Mes2C6H3 with Mes = 2,4,6-Me3C6H2; Tph = 2-TripC6H4 with Trip = 2,4,6-iPr3C6H2) or,
depending on the molar ratio, the solvated complex [Dmp(Tph)N3YbC6F5(THF)].
创建时间：
2016-05-05
