Direct Arylation of Polycyclic Aromatic Hydrocarbons through Palladium Catalysis
收藏NIAID Data Ecosystem2026-03-07 收录
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We have discovered that the combination of Pd(OAc)2/o-chloranil can catalyze the direct C–H bond arylation of polycyclic aromatic hydrocarbons (PAHs) with arylboroxins that occurs selectively at the K-region. The sequential integration of Pd-catalyzed direct arylation of PAHs and FeCl3-mediated cyclodehydrogenation is effective in rapidly extending a parent PAH π-system with high directionality.
创建时间：
2011-07-20
