Chiral Pyrrolidines and Piperidines from Enantioselective Rhodium-Catalyzed Cascade Arylative Cyclization
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下载链接:
https://figshare.com/articles/dataset/Chiral_Pyrrolidines_and_Piperidines_from_Enantioselective_Rhodium_Catalyzed_Cascade_Arylative_Cyclization/2180701
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资源简介:
A new rhodium-catalyzed
asymmetric arylative cyclization of nitrogen-tethered
alkyne-enoate with arylboronic acids is described. In this process
two new carbon–carbon bonds and one stereocenter are formed,
providing access to pyrrolidines and piperidines with good enantioselectivities
by to the use of C1-symmetric chiral monosubstituted
diene ligands.
创建时间:
2016-02-13



