Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)2B(CO)]+ Stabilized by Three Neutral Ligands
收藏Figshare2017-09-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_Structure_and_Reactivity_of_a_Borylene_Cation_NHSi_sub_2_sub_B_CO_sup_sup_Stabilized_by_Three_Neutral_Ligands/5402518
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资源简介:
A borylene cation stabilized by bis(silylene) and carbon monoxide was prepared and structurally characterized via the reaction of bis(silylene)-stabilized bromoborylene with W(CO)6. This is the first example of a borylene cation coordinated by three neutral ligands, which can be viewed as a cationic form of a long-sought Lewis base-stabilized zerovalent boron compound. This cation can cleave dihydrogen.
创建时间:
2017-09-13



