Data for Integrated CO2 capture and dynamic catalysis for CO2 recycling in a microbrewery

In this study, we used fermentation off-gases from a brewery for integrated CO2 capture and utilisation in order to produce CH4 with a dual-function material (DFM) containing NiRu as catalyst and dispersed CaO as adsorbent. CH4 was produced from captured CO2 via 2 pathways (fast and slow), proceeding through formyl intermediates according to the operando DRIFTS-MS results. The NiRuCa DFM showed a stable CH4 capacity over 8 cycles (105 μmol/gDFM) with fermentation off-gases being used as a CO2 capture feed. H2O and O2, which were present in small amounts in the emissions feed, resulted in the passivation of Ni in the form of a NiO layer that protected the DFM from excessive oxidation and deactivation. This work constitutes a first in terms of validating the use of DFMs with real industrial emissions, and it directly correlates the DFM activity performance with its reaction mechanism and intermediate species.<br>Those are the data generated for our collaborative project with Spain. All the data are given in excel files except of some figures that are png format. The uploaded data also include the data used in the supplementary information and those figures and tables are denoted with an 'S' before the number. The data include the activity data of a sample under real conditions, its reaction mechanism under ideal and realistic conditions, and its physiochemical characterisation.